The quest for learning more about the minute intricacies of the universe has fascinated mankind since ages. From stars to planets and asteroids to exoplanets, each research endeavor in astronomy has supplemented our knowledge about the cosmos. NASA's Kepler Mission is one monumental step in this direction wherein, telescopes conduct a survey of the Milky Way galaxy and try to identify thousands of earth-size and other smaller planets in or near the habitable zone, so as to determine the thousands or even millions of stars in our galaxy that might have such orbiting planets. Exoplanet is any new planet outside the solar system which orbits a star. Identifying new exoplanets gives us a chance to precisely understand the planet formation processes. Earlier, it was a laborious endeavour to mine the mission data using traditional algorithms and churn out the possible exoplanets. Ever since the advent of various machine learning algorithms, this process has become quite seamless. However, not all algorithms give equal and promising results when it comes to analysing different types of data. A comparative study of algorithms helps in this regard, thereby identifying the pros and cons of different algorithms for analysing certain forms of data. In this paper, we initially focus on feature set reduction using principal component analysis and thereafter make a detailed comparative analysis of ML algorithms for the identification of exoplanets, in the NASA Kepler mission data. © 2022 Elsevier B.V.. All rights reserved.